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2,2,3,4,4,4-Hexafluorobutyl methacrylate (HFBMA) is a fluorinated monomer that is used in the synthesis of well-defined organic/inorganic hybrid fluorinated star polymers. It possesses unique properties due to the presence of fluorine atoms, which contribute to its chemical stability, low surface energy, and high thermal resistance.

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  • 36405-47-7 Structure

  • Basic information

    1. Product Name: 2,2,3,4,4,4-Hexafluorobutyl methacrylate
    2. Synonyms: 2,2,3,4,4,4-HEXAFLUOROBUTYL METHACRYLATE;1H,1H,3H-HEXAFLUOROBUTYL METHACRYLATE;DAIKIN M-7310;2-METHYL-ACRYLIC ACID 2,2,3,4,4,4-HEXAFLUORO-BUTYL ESTER;methacrylic acid 2,2,3,4,4,4-hexafluorobutyl ester;2,2,3,4,4,4-Hexafluorobutyl methacrylate 99%;2,2,3,4,4,4-Hexafluorobutylmethacrylate99%;2-Propenoic acid,2-methyl-,2,2,3,4,4,4-hexafluorobuthyl ester
    3. CAS NO:36405-47-7
    4. Molecular Formula: C8H8F6O2
    5. Molecular Weight: 250.14
    6. EINECS: -0
    7. Product Categories: monomer;C8 to C9Monomers;Fluorine-Containing Monomers for 157 nm UV Lithography Resist PolymersPhotonic and Optical Materials;Low Refractive Index Monomers;Acrylic Monomers;Carbonyl Compounds;Esters;Fluorinated AcrylicsSelf Assembly&Contact Printing;Lithography Monomers;Waveguide Materials;Acrylic Monomers;Building Blocks;C8 to C9;Carbonyl Compounds;Chemical Synthesis;Contact Printing;Fluorinated Acrylics;Fluorine-Containing Monomers for 157 nm UV Lithography Resist Polymers;Lithography Monomers;Low Refractive Index Monomers;Materials Science;Micro/NanoElectronics;Monomers;Organic and Printed Electronics;Organic Building Blocks;Photonic and Optical Materials;Polymer Science;Self Assembly &Waveguide Materials
    8. Mol File: 36405-47-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 158 °C(lit.)
    3. Flash Point: 134 °F
    4. Appearance: clear colorless liquid
    5. Density: 1.348 g/mL at 25 °C(lit.)
    6. Vapor Pressure: 0.25 psi ( 20 °C)
    7. Refractive Index: n20/D 1.361(lit.)
    8. Storage Temp.: 0-6°C
    9. Solubility: N/A
    10. Water Solubility: Difficult to mix in water.
    11. Sensitive: Lachrymatory
    12. BRN: 2725177
    13. CAS DataBase Reference: 2,2,3,4,4,4-Hexafluorobutyl methacrylate(CAS DataBase Reference)
    14. NIST Chemistry Reference: 2,2,3,4,4,4-Hexafluorobutyl methacrylate(36405-47-7)
    15. EPA Substance Registry System: 2,2,3,4,4,4-Hexafluorobutyl methacrylate(36405-47-7)

  • Safety Data

    1. Hazard Codes: Xi,F
    2. Statements: 36/37/38
    3. Safety Statements: 26-27-36/37/39-37/39
    4. RIDADR: UN 3272 3/PG 3
    5. WGK Germany: 3
    6. RTECS:
    7. HazardClass: 3
    8. PackingGroup: III
    9. Hazardous Substances Data: 36405-47-7(Hazardous Substances Data)

36405-47-7 Usage

Uses

Used in Coatings Industry:
2,2,3,4,4,4-Hexafluorobutyl methacrylate is used as an epoxy thinner and as a modifier for (meth)acrylate resins. Its incorporation into these resins enhances their properties, such as chemical resistance, adhesion, and durability, making them suitable for various coating applications.
Used in Polymer Synthesis:
2,2,3,4,4,4-Hexafluorobutyl methacrylate is used as a monomer in the synthesis of well-defined organic/inorganic hybrid fluorinated star polymers via atom transfer radical polymerization (ATRP). The use of octa(aminophenyl)silsesquioxane (OAPS) nano-cage as an initiator allows for the creation of these star polymers with controlled molecular architecture and improved properties.
These star polymers have potential applications in various fields, such as high-performance materials, biomaterials, and drug delivery systems, due to their unique structure and properties derived from the incorporation of fluorine atoms and the hybrid organic/inorganic nature of the polymers.

Check Digit Verification of cas no

The CAS Registry Mumber 36405-47-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,4,0 and 5 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 36405-47:
(7*3)+(6*6)+(5*4)+(4*0)+(3*5)+(2*4)+(1*7)=107
107 % 10 = 7
So 36405-47-7 is a valid CAS Registry Number.
InChI:InChI=1/C8H8F6O2/c1-4(2)5(15)16-3-7(10,11)6(9)8(12,13)14/h6H,1,3H2,2H3/t6-/m1/s1

36405-47-7 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
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  • Detail

  • TCI America

  • (H1555)  2,2,3,4,4,4-Hexafluorobutyl Methacrylate (stabilized with MEHQ)  >98.0%(GC)

  • 36405-47-7

  • 5g

  • 220.00CNY

  • Detail

  • TCI America

  • (H1555)  2,2,3,4,4,4-Hexafluorobutyl Methacrylate (stabilized with MEHQ)  >98.0%(GC)

  • 36405-47-7

  • 25g

  • 790.00CNY

  • Detail

  • TCI America

  • (H1555)  2,2,3,4,4,4-Hexafluorobutyl Methacrylate (stabilized with MEHQ)  >98.0%(GC)

  • 36405-47-7

  • 100g

  • 2,890.00CNY

  • Detail

  • Alfa Aesar

  • (L09543)  2,2,3,4,4,4-Hexafluorobutyl methacrylate, 96%, stab.   

  • 36405-47-7

  • 5g

  • 262.0CNY

  • Detail

  • Alfa Aesar

  • (L09543)  2,2,3,4,4,4-Hexafluorobutyl methacrylate, 96%, stab.   

  • 36405-47-7

  • 25g

  • 986.0CNY

  • Detail

  • Alfa Aesar

  • (L09543)  2,2,3,4,4,4-Hexafluorobutyl methacrylate, 96%, stab.   

  • 36405-47-7

  • 100g

  • 2845.0CNY

  • Detail

  • Aldrich

  • (371971)  2,2,3,4,4,4-Hexafluorobutylmethacrylate  98%

  • 36405-47-7

  • 371971-5G

  • 583.83CNY

  • Detail

36405-47-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,2,3,4,4,4-Hexafluorobutyl Methacrylate

1.2 Other means of identification

Product number -
Other names 2,2,3,4,4,4-Hexafluorobutyl methacrylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:36405-47-7 SDS

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